Reference of 114615-82-6, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 114615-82-6, C12H28NO4Ru. A document type is Article, introducing its new discovery.
Selectivity Modulation of the Ley?Griffith TPAP Oxidation with N-Oxide Salts
A wide variety of novel non-hygroscopic N-oxide tetraphenylborate salts were synthesized and evaluated as co-oxidants in the Ley?Griffith (TPAP) oxidation of benzylic and allylic alcohols under non-anhydrous conditions. The novel DABCOO¡¤TPB (2:1) salt was herein unearthed as a viable competitor to the first-generation NMO¡¤TPB (2:1) salt, but more importantly gave increased performance under oxidative competition. X-ray crystal structure analysis and NMR spectroscopy revealed that depending on the crystallization conditions 1:1, 2:1 or 3:2 N-oxide?tetraphenylborate salts could be formed.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI