In an article, published in an article, once mentioned the application of 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer,molecular formula is C12H12Cl4Ru2, is a conventional compound. this article was the specific content is as follows.Application In Synthesis of Dichloro(benzene)ruthenium(II) dimer
Unique solubility of polyoxoniobate salts in methanol: Coordination to cations and POM methylation
Sodium salts of hybrid organometallic POM complexes consisting of [M6O19]8- (M = Nb, Ta) and half-sandwich fragments {Cp?M}2+ (Cp? = eta5-C5(CH3)5; M = Rh, Ir) and {(C6H6)Ru}2+ dissolve only in one organic solvent, that is, in methanol. From methanolic solutions, crystals of Na4[trans-{(C6H6)Ru}2Nb6O19]¡¤14.125MeOH¡¤2H2O (1), K4[trans-{Cp?Rh}2Nb6O19]¡¤4MeOH¡¤10H2O (2) and K4[trans-{Cp?Ir}2Nb6O19]¡¤10MeOH¡¤4H2O (3) were isolated and characterized by X-ray analysis. Methoxo species [{LM?}2M6O19-n(OCH3)n] (n = 1-3) were detected in solution by ESI-MS and NMR, and they account only for about half of the total speciation in the solution. DFT calculations were used to calculate 13C NMR chemical shifts in the methoxo complexes and to assess their relative stability. Reasons for the preferred solubility in methanol are discussed.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI