In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.HPLC of Formula: C41H35ClP2Ru
Mono and dinuclear complexes of half-sandwich platinum group metals (Ru, Rh and Ir) bearing a flexible pyridyl-thiazole multidentate donor ligand
The mononuclear cationic complexes [(eta6-C6H6)RuCl(L)]+ (1), [(eta6-p-iPrC6H4Me)RuCl(L)]+ (2), [(eta5-C5H5)Ru(PPh3)(L)]+ (3), [(eta5-C5Me5)Ru(PPh3)(L)]+ (4), [(eta5-C5Me5)RhCl(L)]+ (5), [(eta5-C5Me5)IrCl(L)]+ (6) as well as the dinuclear dicationic complexes [{(eta6-C6H6)RuCl}2(L)]2+ (7), [{(eta6-p-iPrC6H4Me)RuCl}2(L)]2+ (8), [{(eta5-C5H5)Ru(PPh3)}2(L)]2+ (9), [{(eta5-C5Me5)Ru(PPh3)}2(L)]2+ (10), [{(eta5-C5Me5)RhCl}2(L)]2+ (11) and [{(eta5-C5Me5)IrCl}2(L)]2+ (12) have been synthesized from 4,4?-bis(2-pyridyl-4-thiazole) (L) and the corresponding complexes [(eta6-C6H6)Ru(mu-Cl)Cl]2, [(eta6-p-iPrC6H4Me)Ru(mu-Cl)Cl]2, [(eta5-C5H5)Ru(PPh3)2Cl)], [(eta5-C5Me5)Ru(PPh3)2Cl], [(eta5-C5Me5)Rh(mu-Cl)Cl]2 and [(eta5-C5Me5)Ir(mu-Cl)Cl]2, respectively. All complexes were isolated as hexafluorophosphate salts and characterized by IR, NMR, mass spectrometry and UV-vis spectroscopy. The X-ray crystal structure analyses of [3]PF6, [5]PF6, [8](PF6)2 and [12](PF6)2 reveal a typical piano-stool geometry around the metal centers with a five-membered metallo-cycle in which 4,4?-bis(2-pyridyl-4-thiazole) acts as a N,N?-chelating ligand.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI