In an article, published in an article, once mentioned the application of 246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium,molecular formula is C46H65Cl2N2PRu, is a conventional compound. this article was the specific content is as follows.HPLC of Formula: C46H65Cl2N2PRu
A facile domino metathetic route to a thapsigargin skeleton
A facile synthesis of a 5,7,5-fused ring system that is present in thapsigargins belonging to a novel family of sequiterpene lactones, guainanolides, using domino enyne – RCM was studied. The synthesis began with the readily available ketone. Addition of allenyl Grignard reagent at low temperature afforded the tertiary alcohol in good yield. Selective removal of the more exposed acetonide group followed by cleavage of the diol with silica gel supported NaIO4 provided the first key intermediate aldehyde in high yield. The stereochemistry of the Grignard reaction was tentatively assigned in a scheme based on the Felkin-Anh model.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI