37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, Computed Properties of C12H12Cl4Ru2
Specific reactivity of SH versus OH functions towards dinuclear arene ruthenium units: Synthesis of cationic complexes of the type [(arene)2Ru2(SR)3]+
The reaction of [(arene)RuCl2]2 (arene = C6H6, p-Me-C6H4-iPr, C6Me6) with p-thiocresol, 2-mercaptoethanol and p-mercaptophenol in refluxing ethanol gives the tris-thiolato complexes [(arene)2Ru2(SR)3]+ (R =p-C6H4-Me, CH2CH2OH, p-C6H4OH) which can be isolated as the chloride salts. The remarkable selectivity of (arene)ruthenium units for SH versus OH functions reflects the affinity of ruthenium towards sulfur.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI