Application of 32993-05-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery.
Selenolatovinylidene complexes: Metal-mediated alkynyl selenoether rearrangements
The reactions of [RuCl2(PPh3)3] and [RuCl-(PPh3)2(eta-C5H5)] with PhC?CSeiPr provide the selenolatovinylidene complexes [RuCl2{=C=C(SeiPr)Ph}(PPh3)2] and [Ru{=C=C(SeiPr)Ph}(PPh3)2(eta-C 5H5)]+. The former, being coordinatively unsaturated, readily reacts with nitrogen and phosphorus donor ligands with retention of the selenolatovinylidene moiety; however, pi-acid ligands induce facile elimination of PhC?CSeiPr.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI