Related Products of 37366-09-9. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer. In a document type is Article, introducing its new discovery.
Efficient preparation of chiral non-racemic sulfur compounds
p-Menthane-3-carboxaldehyde serves as an efficient chiral auxiliary in the preparation of chiral non-racemic S-alkylthiocarbamates or 5-dithiocarbonates via the 3,3-sigmatropic rearrangement of the corresponding alkylthionocarbamates or xanthates. The transfer of chirality during rearrangement is complete, and the final products possess a chiral tertiary or quaternary carbon bearing sulfur. The rearranged products are then transformed into enantiopure cyclic or acyclic sulfur-containing products, depending on the means of clivage of the auxiliary. The synthesis of a potent MMP-13 inhibitor is presented.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI