Synthetic Route of 301224-40-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 301224-40-8, Name is (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride
A practical and highly active ruthenium-based catalyst that effects the cross metathesis of acrylonitrile
The highest initiation rate of any reported ruthenium-based catalyst was found for the new olefin-metathesis catalyst [(H2IMes)(3-Br-py)2(Cl)2Ru=CHPh] (1), which was synthesized in one step from commercially available reagents. Complex 1 is highly efficient for the cross metathesis of acrylonitrile, which is generally a poor substrate for metathesis reactions (e.g., see scheme). Mes = 2,4,6-trimethylphenyl.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI