In an article, published in an article, once mentioned the application of 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer,molecular formula is C12H12Cl4Ru2, is a conventional compound. this article was the specific content is as follows.Quality Control of: Dichloro(benzene)ruthenium(II) dimer
Synthesis and characterization of two novel, mono-lacunary Dawson polyoxometalate-based, water-soluble organometallic ruthenium(II) complexes: Molecular structure of [{(C6H6)Ru(H2O)} (alpha2-P2W17O61)]8-
The synthesis and structural characterization of a novel class of mono-lacunary Dawson polyoxometalate-(POM-)based, water-soluble organometallic complexes, which are expected to be effective homogeneous oxidation catalyst precursors in water, is described. The organometallic complexes K 8[{(C6H6)Ru(H2O)} (alpha2-P2W17O61)]¡¤12H 2O (1) and K8[{(p-cymene)Ru(H2O)} (alpha2-P2W17O61)]¡¤16H 2O (2) were successfully prepared by direct reactions of the mono-lacunary Dawson POM K10[alpha2-P2W 17O61]¡¤19H2O with the organometallic precursors [(C6H6)RuCl2]2 and [(p-cymene)RuCl2]2, respectively, in aqueous media and characterized by complete elemental analysis, thermogravimetric and differential thermal analyses (TG/DTA), and FT-IR and solution (1H, 13C, 31P, and 183W) NMR spectroscopy. The molecular structure of [{(C6H6)Ru(H2O)} (alpha2-P2W17O61)]8- (1a), in which the binding of the cationic organometallic group {(C 6H6)Ru(H2O)}2+ occurs through two oxygen atoms of the four available oxygen atoms in the mono-lacunary site of the POM, resulting in overall C1 symmetry, was successfully determined by single-crystal X-ray analysis. Interestingly, the hydrophilicity of the organometallic precursors is greatly enhanced by binding to a mono-lacunary Dawson POM with higher hydrophilicity. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI