Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, Safety of Dichloro(benzene)ruthenium(II) dimer.
Convenient synthesis of tris-heteroleptic ruthenium(II) polypyridyl complexes
A convenient synthesis of tris-heteroleptic polypyridyl [Ru(pp)(pp?)(pp?)]2+ complexes is reported (where pp,pp?, and pp? represent three different polypyridyl ligands). Photolysis of [BzRu(pp)Cl]Cl (Bz = eta6-C6H6) gives a mixture of Ru(pp)(CH3CN)2Cl2 and [Ru(pp)(CH3CN)3Cl]Cl. Refluxing this mixture with pp? yields Ru(pp)(pp?)Cl2. Finally, refluxing Ru(pp)(pp?)Cl2 with pp? in a 75% ethanol/water solution gives [Ru(pp)(pp?)(pp?)]2+. No ligand scrambling is observed. The complexes are characterized by 1H NMR, elemental analysis, FAB-MB, UV-vis and emission spectroscopy, and cyclic voltammetry.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Safety of Dichloro(benzene)ruthenium(II) dimer. In my other articles, you can also check out more blogs about 37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI