Reference of 37366-09-9. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer
Syntheses, structures, and catalytic properties of two arene-ruthenium(II) complexes bearing N-(2-pyridinyl)aminodiphenylphosphine sulfide ligands
Treatment of [(arene)Ru(mu-Cl)Cl]2 with Ph2P(S)NH(2-py) in the presence or absence of base gave two arene-ruthenium(II) complexes [(eta6-p-cymene)Ru{kappa2-N,N-Ph2P(S)N(2-py)}Cl] (1) and [(eta6-benzene)Ru{kappa1-N-Ph2P(S)NH(2-py)}Cl2] (2), which have been characterized by infrared, nuclear magnetic resonance spectroscopies, and mass spectrometry along with microanalyses. Crystal structures of Ph2P(S)NH(2-py) ¡¤ 1/4C6H14, 1 and 2 ¡¤ 1/2CH2Cl2 were determined by single-crystal X-ray diffraction. Two arene-ruthenium(II) complexes were tested as precatalysts for the transfer hydrogenation of acetophenone to give 1-phenyl ethanol.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI