In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.Application In Synthesis of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Chiral cyclopentadienyl ruthenium(II) complexes with P,P-ligands derived from (1R,2R)-1,2-diaminocyclohexane: Synthesis, crystal structures and catalytic activity in Diels-Alder reactions
Chiral cyclopentadienyl ruthenium(II) complexes [CpRu(L1-L3)Cl] (5-7) have been prepared by reaction of [CpRu(PPh3)2Cl] with chiral P,P-ligands (1R,2R)-1,2-bis(diphenylphosphinamino)cyclohexane (L1), N,N?-[bis-(3,3?-bis-tert-butyl-5,5?-bis-methoxy-1, 1?-biphenyl-2,2?-diyl)phosphite]-(1R,2R)-1,2-diaminocyclohexane (L2) and N,N?-[bis-(R)-1,1?-binaphtyl-2,2?-diyl)phosphite]-(1R,2R) -1,2-diaminocyclohexane (L3). The molecular structures of 5 and 6 have been determined by single-crystal X-ray analysis. Studies on catalytic activity of the cations derived from (5-7) by treatment with AgSbF6, are also reported.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI