A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article£¬once mentioned of 32993-05-8, Computed Properties of C41H35ClP2Ru
Reactivity studies of cyclopentadienyl bis(triphenylphosphine)ruthenium(II) complex towards some polypyridyl ligands
The reaction of [CpRu(PPh3)2Cl] (1) (Cp=eta5-C5H5) with excess of some potentially bridging ligands viz. 2,3-bis(alpha-pyridyl)pyrazine (bpp), 2,3-bis(alpha-pyridyl)quinoxaline (bpq), 1,3,5-tris(pyridyl)-2,4,6-triazine (tptz) and 2,3,5,6-tetrakis(pyridyl)pyrazine (tppz) yielded cationic mononuclear complexes of the type [CpRu(PPh3)(bpp)]+ (2), [CpRu(PPh3)(bpq)]+ (3), [CpRu(PPh3)(tptz)] + (4) and [CpRu(PPh3)(tppz)]+ (5), respectively. These complexes have been isolated as hexafluorophosphate salts. They were characterized by FT-IR, 1H NMR and 31P { 1H} NMR spectroscopy. The molecular structures of representative complexes 3 and 5 have been solved by single crystal X-ray crystallography.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C41H35ClP2Ru. In my other articles, you can also check out more blogs about 32993-05-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI