Related Products of 92361-49-4. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 92361-49-4, Name is Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.
An unusual Cu2Ru2 cluster containing a tetrameric phenylethynyl ligand
The reaction between RuCl(PPh3)2Cp* and {Cu(CCPh)}n in refluxing benzene afforded Ru2Cu2(C2Ph)5H2(Cl)(PPh3)Cp*2, which contains an unusual tetramer of the phenylethynyl group which interacts with an Ru…Cu…Cu…Ru chain. The second Ru atom is part of a ruthenocenyl moiety which interacts weakly with the second Cu atom, and bears a vinylidene which bridges an Ru-Cu vector. The structure of a second modification of Ru(C{triple bond, long}CPh)(CO)(PPh3)Cp* is also reported.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI