Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, COA of Formula: C12H12Cl4Ru2.
Organometallic ionic liquids from half-sandwich Ru(II) complexes with various chelating ligands
Salts comprising of cationic half-sandwich Ru(II) complexes with various chelating ligands and the bis(trifluoromethanesulfonyl)amide anion (Tf2N-) were prepared. These salts can be represented as [(arene)RuCl(L-L)][Tf2N] (arene = C6Me5Bu, C6Me6, p-cymene, C6H6; L-L = 2-Py-CH2NHCMe2Et, 2-Py-CH=NC6H13, H13C6NHCH2CH2NHC6H13, Me2NCH2CH2SC4H9, Me2CN=CHCH=NCMe2). Two of the eight salts are liquids at room temperature (?20 C), while the other salts are solids with melting points of 60-130 C. Upon cooling from the melt, most salts exhibited glass transitions between -30 C and -5 C. The salts were found to catalyze the oxidation of cyclohexanol although decomposition occurred during the reaction. Crystal structures of related salts were also determined.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.COA of Formula: C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI