If you are interested in 15746-57-3, you can contact me at any time and look forward to more communication.Electric Literature of 15746-57-3
Electric Literature of 15746-57-3. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II). In a document type is Article, introducing its new discovery.
High-Energy Metal to Ligand Charge-Transfer States in Ruthenium-Diimine Complexes
Earlier emission and absorption contours for the 2+ complex were anormalous.In addition, the photoselection spectra (emission and excitation) differ from that found previously for (dpy)2 complexes.Speculation was that these differences result from the high-energy metal to ligand charge-transfer (MLCT) state in this complex.Consquently, a number of bis Ru(II) chelate complexes with varying energy MLCT states were examined to rationalize these experimental results.The result with use of perturbation theory demonstrate an interaction between the singlet MLCT states and ?-?* states for these materials.The correlations of the emission Stokes shift and the zero-order energy of the singlet MLCT state indicate that singlet absorption and triplet emission derive from states of different orbital configuration.Predictions of the symmetry of the absorbing singlet and emitting triplet from a simple model are consistent with the results obtained earlier from the interchromophoric coupling model.
If you are interested in 15746-57-3, you can contact me at any time and look forward to more communication.Electric Literature of 15746-57-3
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI