Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn¡¯t involve a screen. 37366-09-9, C12H12Cl4Ru2. A document type is Article, introducing its new discovery., Safety of Dichloro(benzene)ruthenium(II) dimer
Preparation and study of functionalized 1,2,4-triazine derivatives of the (eta6-arene)Ru(II) (arene=benzene or p-cymene) and (eta5-C5Me5)Rh(III) moieties
In dichloromethane the complexes [{(eta6-arene)RuCl(mu-Cl)}2] (arene=benzene or p-cymene) and [{(eta5-C5Me5)RhCl(mu-Cl)}2] react with the triazines 4-amino-6-methyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine (3-S-ATAZ), 4-amino-6-methyl-5-oxo-3-phenylamino-4,5-dihydro-1,2,4-triazine (3-PhNH-ATAZ) and 4-amino-6-methyl-5-oxo-3-amino-4,5-dihydro-1,2,4-triazine (3-NH2-ATAZ) to form the corresponding complexes [(eta6-arene)RuCl(triazine)]Cl. The new compounds have been characterized by conductance measurements and spectroscopic (IR, (1)H, (13)C) methods. In every case the triazine acts as a chelating bidentate ligand, which has been confirmed by a single-crystal diffraction study carried out with [(eta5-C5Me5)RhCl(3-PhNH-ATAZ)]PF6*H2O.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI