Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 20759-14-2, Name is Ruthenium(III) chloride hydrate, Quality Control of: Ruthenium(III) chloride hydrate.
Synthesis and characterization of novel oxime-imine ligands and their heteronuclear ruthenium(III) complexes
Vicinal carbonyl oxime (HL1) and oxime-imine (H 2L2) ligands and their mononuclear Ru(III) and Cu(II), heterodinuclear Ru(III)-Mn(II), Ru(III)-Ni(II), Ru(III)-Cu(II), and heterotrinuclear Ru(III)-Cu(II)-Ru(III) chelates were synthesized and characterized by elemental analysis, molar conductivity, IR, ESR, ICP-OES, magnetic moment measurements, and thermal analyses studies. The free ligands were also characterized by 1H NMR spectra. The carbonyl-oxime ligand coordinates through the oxygen of =N-OH to form a six-membered chelate ring. The quadridentate tetraaza ligand (H2L2) obtained by condensing of the bidentate ligand 1-p-diphenylmethane-2-hydroxyimino-2-(1- naphthylamino)-1-ethanone (HL1) with 1,2-phenylenediamine coordinates with Ru(III) through its nitrogen donors in the equatorial position with the loss of one of the oxime protons and concomitant formation of an intramolecular hydrogen bond. Stoichiometric and spectral results of the metal complexes indicated that the metal: ligand ratios in the mononuclear complexes of the ligand (HL1) were found to be 1: 2, while these ratios were 1: 1 in the mononuclear complexes of the ligand (H2L2). The metal: ligand ratios of the dinuclear complexes were found to be 2: 1, and this ratio was 3: 2 in the trinuclear complex.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: Ruthenium(III) chloride hydrate. In my other articles, you can also check out more blogs about 20759-14-2
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI