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Synthesis of Ru- and Os-complexes of pi-conjugated oligomers of 2,2′- bipyridine and 5,5′-bipyrimidine. Optical properties and catalytic activity for photoevolution of H2 from aqueous media
Oligomers of 2,2′-bipyridine (Oligo-bpy) and 5,5′-bipyrimidine (Oligo- bpym) with a linear structure have been prepared by an organometallic C-C coupling reaction. The oligomeric chelating ligands have a molecular weight of about 1500 corresponding to about 10 chelating bpy or bpym units, and form soluble complexes with [M(bpy)2]2+ (M = Ru or Os). The UV-vis absorption spectra of the metal complexes of Oligo-bpy exhibit a pi-pi* transition band at 3552¡À6 nm and a peak at 453¡À18 nm assigned to a MLCT absorption. The UV- vis spectra of the metal complexes of Oligo-bpym also show an absorption peak attributed to the MLCT band. The water-soluble Ru complex of Oligo-bpy catalyzes visible-light-induced H2 evolution from aqueous media in the presence of Pt cocatalyst and triethylamine.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI