Application of 37366-09-9, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 37366-09-9, C12H12Cl4Ru2. A document type is Article, introducing its new discovery.
The design and synthesis of thiophene-based ruthenium(II) complexes as promising sensitizers for dye-sensitized solar cells
A new series of promising synthetically facile cycloruthenated thiophene-based sensitizers have been developed and fully characterized by UV?vis spectroscopy, NMR and cyclic voltammetric studies. The synthesized dyes have broad MLCT bands spanning the visible spectrum, with high extinction coefficients. The energies of the molecular orbitals for the isolated molecules of the complexes and densities of occupied states were determined. The cycloruthenated compounds contains ortho-metallated thiophene moiety substituted by N-(methyliden)aniline or pyridine-2-yl at the ortho-position. Having 4,4?-dicarboxy-2,2?-bipyridine as the linker and auxiliary ligands and anchored to nanocrystalline TiO2 films, they achieve efficient sensitization in the visible range and display an overall conversion efficiency of 5.3% under standard AM 1.5 sunlight.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI