Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 10049-08-8, Name is Ruthenium(III) chloride, name: Ruthenium(III) chloride.
Ruthenium complexes of the scorpionate ligand bis(3,5-dimethylpyrazol-1-yl) -dithioacetate and the effect of nitric oxide coordination
Six new ruthenium(II) complexes with the scorpionate ligand bis(3,5-dimethylpyrazol-1-yl)dithio-kappa3N,N,S-acetate (bdmpzdta) were obtained by treatment of the ligand with RuCl3 or [RuCl 3(NO)] in 1:1 or 2:1 molar ratios in the presence or absence of ethylenediamine. In all six complexes the pyrazolic rings lie in the equatorial plane. The mononitrosyl complexes present a sharp nu(NO) band in the range 1864-1859 cm-1 for samples prepared either as KBr tablets or dichloromethane solutions. In the case of [Ru(NO)-(bdmpzdta)2]Cl (7), the dithiocarboxylate group of one of the ligands is not coordinated (kappa2N,N). In the other five complexes, however, bdmpzdta behaves as a kappa3N,N,S scorpionate ligand. When the complexes obtained from RuCl3 were dissolved in dichloromethane and NO was bubbled through the solution, a high degree of coordination of NO+ was observed, according to IR, UV and voltammetric studies. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.name: Ruthenium(III) chloride. In my other articles, you can also check out more blogs about 10049-08-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI