Electric Literature of 15746-57-3, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 15746-57-3, C20H16Cl2N4Ru. A document type is Article, introducing its new discovery.
Ruthenium carbonyl compounds containing polypyridine ligands as catalysts in the reaction of N-benzylideneaniline hydrogenation
The synthesis and characterization of ruthenium complexes containing polypyridine ligands: Ru(dppz)(PPh3)2Cl2, Ru(bpy)(PPh3)2Cl2, Ru(phen)(PPh 3)2Cl2, Ru(dppz-Cl)(PPh3) 2Cl2, Ru(phen)(CO)2Cl2, Ru(bpy)(CO)2Cl2 and Ru(dppz)(CO)2Cl2 (where dppz: dipyrido[3,2-a:2?,3?-c]phenazine, dppz-Cl: 10-chlororodypirido[3,2-a:2?,3?-c]phenazine, phen: 1,10-phenanthroline and bipy: 2,2?-bipyridine) are reported. The ruthenium complexes show high activity as catalysts in the hydrogenation reaction of N-benzylideneaniline and the hydrogen transfer reaction. The products of the catalysis were obtained with conversions between 21 and 91% after 2 h of reaction. The Ru(phen)(CO)2Cl2 complex was the catalyst that showed the highest conversion (91%) for the hydrogenation of N-benzylideneaniline. The complexes Ru(dppz)(PPh3)2Cl 2, Ru(bpy)(PPh3)2Cl2 and Ru(dppz)(CO)2Cl2 showed 99% conversion in the hydrogen transfer reaction.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI