The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article£¬once mentioned of 32993-05-8, HPLC of Formula: C41H35ClP2Ru
Hydride Reduction of the Cations <(eta5-C5H5)Fe<(Ph2PCH2)3CMe>>PF6, <(eta5-C5H5)Ru<(Ph2PCH2CH2)2PPh>>PF6, and <(eta5-C5H5)Ru<(Ph2PCH2)3CMe>>PF6: Regioselectivity and Mechanism
Reduction of the cation <(eta5-C5H5)Fe(tripod)>PF6 with lithium aluminium hydride gives (eta5-C5H5)FeH(tripod) via an SN1 mechanism, involving prior dissociation of a phosphine ligand leading to direct attack of hydride on the metal, in contrast with the related ruthenium cations <(eta5-C5H5)RuL3>PF6 (L3 = triphos or tripod) which give the cyclopentadiene complexes (eta4-C5H6)RuL3 via exo-hydride attack on the cyclopentadienyl ligand
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.HPLC of Formula: C41H35ClP2Ru, you can also check out more blogs about32993-05-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI