A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article£¬once mentioned of 37366-09-9, Application In Synthesis of Dichloro(benzene)ruthenium(II) dimer
Selective hydrogenation of ruthenium acylphosphine complexes
Hydrogenation of a benzene ruthenium chloride dimer in the presence of novel acylphosphine (phosphomide) ligands resulted in the formation of corresponding ruthenium(II)-benzyl phosphine complexes. Here, selective reduction of the carbonyl group to a methylene unit takes place with molecular hydrogen under mild conditions in good yield. This approach provides an alternative synthesis of ruthenium phosphine complexes of benzyl and heterobenzyl phosphine ligands.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Application In Synthesis of Dichloro(benzene)ruthenium(II) dimer, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 37366-09-9, in my other articles.
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI