The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 37366-09-9 is helpful to your research., Electric Literature of 37366-09-9
Electric Literature of 37366-09-9, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article£¬once mentioned of 37366-09-9
Aren- und Cyclopentadienyl-Halbsandwichkomplexe des Rutheniums mit Oximaten, Carboxylaten, Iminen und Azavinylidenen als Liganden
The reaction of (1) with NaON=CRR’ in the presence of KPF6 leads to the formation of the oximatoruthenium(II) complexes PF6 (2-5) in 70-90percent yield.Compound 5 (R=Me, R’=t-Bu) reacts with HN=CPh2 via ligand exchange to give PF6 (8).The azavinylidene complex 8 has also been prepared from the acetatoruthenium derivative PF6 (6), which can be obtained either from 1, CH3CO2Na and KPF6 or from treatment of 5 with an excess of CH3CO2H.The synthesis of the hexamethylbenzeneruthenium compounds PF6 (12-15) is achieved by the reaction of the hydrido(chloro)metal complexes (10, 11) with oximes HON=CR’2 and AgPF6.Nucleophilic addition of H- and CH-3 to the N=C carbon atom of + affords the uncharged imido compounds (16, 17).The cyclopentadienylruthenium complex (23) is prepared from either one of the imino derivatives BF4*0.5CH2Cl2 (22) or (25) on treatment with NaR (R=H, C5H5).Compound 25 reacts in toluene at room temperature by elimination of CH3CO2H to give the five-membered metallaheterocycle (26) which is an isomer of 23.The X-ray structural analysis of 5 reveals the presence of a O,N-bound oximato ligand and a cis position of the C6H6(PiPr3)Ru and t-Bu units at the N=C double bond.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 37366-09-9 is helpful to your research., Electric Literature of 37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI