Archives for Chemistry Experiments of 37366-09-9

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Reference of 37366-09-9. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer

Synthesis of half sandwich platinum group metal complexes containing pyridyl benzothiazole hydrazones: Study of bonding modes and antimicrobial activity

Pyridyl benzothiazole hydrazone derivatives containing ruthenium, rhodium and iridium complexes have been synthesized, characterized and evaluated for antimicrobial activity. Metal precursors of the type [(arene)RuCl2]2(arene = p-cymene, benzene), [Cp?MCl2]2 (M = Rh/Ir) and pyridyl benzothiazole hydrazone ligands (L1 and L2) have been employed in this work. Complexes containing ligands L1 in 1:2 (M:L) ratio yielded only one type of cationic mononuclear complexes whereas ligand L2 in 1:2 (M:L) ratio yielded two types of cationic mononuclear complexes. In same manner ligand L2 in 1:1 (M:L) ratio also yielded two types of binuclear complexes with different modes of binding. All these complexes have been characterized by analytical, spectroscopic and single-crystal X-ray diffraction studies. Antibacterial studies of ligands and complexes have been carried out and were found to exhibit potent activity towards gram-positive and gram-negative bacteria.

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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI