A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article£¬once mentioned of 32993-05-8, Recommanded Product: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Reactions of furylruthenium complexes with oxygen and trimethylsilyl azide
The reaction of the (alpha-alkoxyfuryl)ruthenium complexes 4 with oxygen opens the five-membered furyl ring to give the addition product [Ru]O 2CCR=CHCO2CH3, (5, [Ru] = Cp(PPh 3)2Ru). Further reactions of 5 with CH3I and with organic acid gave CH3O2CCR=CHCO2CH 3, (6), and HO2CCR=CHCO2CH3, (7), respectively. The reaction of 4 with TMSN3 [TMS = (CH 3)3Si] gives the ruthenium azide [Ru]-N3 and alpha-alkoxyfuran, which is readily hydrolyzed to lactone in acidic medium. Treatment of the cyclopropenylruthenium complex 11b containing a methyl crotonate group with TMSN3 affords the five-membered-ring triazole and [Ru]-CN. In this reaction cleavage of the C=C double bond of the three-membered ring could be caused by consecutive additions of TMSN3 to olefinic carbon atoms of intermediates formed during the reaction. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Recommanded Product: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In my other articles, you can also check out more blogs about 32993-05-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI