Application of 301224-40-8, An article , which mentions 301224-40-8, molecular formula is C31H38Cl2N2ORu. The compound – (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride played an important role in people’s production and life.
Does the rate of competing isomerisation during alkene metathesis depend on pre-catalyst initiation rate?
Experimental studies of the ring-closing metathesis reaction of 1,8-nonadiene and the ROMP reaction of cycloheptene show that the rate of isomerisation is not correlated to the initiation rate of the pre-catalyst, and that the absence of phosphine leads to a greatly increased rate of isomerisation. A range of pre-catalysts and solvents were probed and it is proposed that the isomerisation is mediated by a ruthenium hydride complex; our results are consistent with the rate-determining formation of such a species, which might be trapped in situ by tricyclohexylphosphane.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 301224-40-8, help many people in the next few years., Application of 301224-40-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI