If you are interested in 15746-57-3, you can contact me at any time and look forward to more communication.Electric Literature of 15746-57-3
Electric Literature of 15746-57-3. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II). In a document type is Article, introducing its new discovery.
Synthesis, structure, redox activity and spectroscopic properties of ruthenium(II) complexes with 3,5-bis(benzothiazol-2-yl)pyrazole, 3,5-bis(benzimidazol-2-yl)pyrazole and 2,2′-bipyridine as co-ligands
Ruthenium(II) complexes of composition <(bipy)2Ru(Hpzbzth)>2*3H2O 1, <(bipy)2Ru(pzbzth)>*2H2O 2, <(bipy)2Ru(pzbzth)Ru(bipy)2>3*H2O 3, <(bipy)2Ru(H3pzbzim)>2*2H2O 4 and <(bipy)2Ru(Hpzbzim)>*2H2O 5, where Hpzbzth=3,5-bis(benzthiazol-2-yl)pyrazole, H3pzbzim=3,5-bis(benzimidazol-2-yl)pyrazole and bipy=2,2′-bipyridine, have been synthesized and characterized. The crystal structure of 3, in which the two metal centres are bridged by the pyrazolate moiety of the pzbzth anion, has been determined. The two RuN6 chromophores in this complex are separated by 4.723(3) Angstroem. From the significant down-field shift of the pyrazolate CH proton in 3 (8.92 ppm) with respect to 1 (7.78 ppm) and 4 (7.82 ppm), the involvement of S…H(C)…S type interaction in 3 has been proposed. The equilibrium constants of the species involving dissociation of the NH protons of the bridging ligand and the change in the oxidation state of ruthenium from +2 to +3 have been determined in acetonitrile-water (3:2) by cyclic voltammetric and spectrophotometric methods. Redox titrations of complexes 1, 3 and 4 by cerium(IV) have revealed that the disappearance of the metal-to-ligand charge transfer band is accompanied by the appearance of the ligand-to-metal charge transfer band at higher wavelengths. In the case of 3, when 1 equivalent of cerium(IV) is added, the mixed-valence Ru(II)Ru(III) species is generated which exhibits an absorption maximum at 950 nm due to the intervalence-transfer transition. The luminescence spectral behaviour of complexes 1-4 has been examined in methanol-ethanol (1:4) solution (at 300 K) as well as in glassy state (at 77 K).
If you are interested in 15746-57-3, you can contact me at any time and look forward to more communication.Electric Literature of 15746-57-3
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI