In an article, published in an article, once mentioned the application of 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer,molecular formula is C12H12Cl4Ru2, is a conventional compound. this article was the specific content is as follows.HPLC of Formula: C12H12Cl4Ru2
Oligomeric (eta6-arene) ruthenium(II) complexes of adenine and adenosine with N6,N7 coordination
Treatment of [{RuCl2(eta6-arene)}2] (arene=p-cymene, C6H6) with adenine (adeH), 9-ethyladenine (9etade) and adenosine (aden) provides the complexes [{Ru(ade) (eta6-p-cymene)}4] (CF3SO3)4 (2), [{Ru(9etadeH_1) (eta6-p-cymene)}3] (CF3SO3)3 (3) and [{Ru(adenH_1) (eta6-C6H6)}3] (CF3SO3)3 (4). The structures of complexes 2 and 3 were established by X-ray structural analysis. 2 crystallises in the tetragonal space group I41/a with a=b=15.870(2), c=35.710(7) A, Z=4; 3 ¡¤ 1.5H2O in the monoclinic space group C2/c with a=35.985(3), b=13.094(2), c=28.406(3) A, Z=8. Common to 2-4 is the participation of N6 and N7 in a five-membered chelate ring, which leads to a characteristic upfield shift in the 1H NMR signal of the pyrimidine proton H2. The tetrameric complex 2 exhibits the mu-1kappaN9:2kappa2N6,N7 coordination mode for the bridging adeninate ligands, the trimeric complexes 3 and 4 the mu-1kappaN1:2kappa2N6,N7 mode for the 9-substituted derivatives.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI