A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II), molecular formula is C20H16Cl2N4Ru. In a Article£¬once mentioned of 15746-57-3, Product Details of 15746-57-3
TTF-annulated phenanthroline and unexpected oxidative cleavage of the C=C bond in its ruthenium(II) complex
Tetrathiafulvalene (TTF) and 1, 10-phenanthroline have been fused together via a simple and efficient synthetic procedure that provides a new bidentate ligand, 40, 50-ethylenedithiotetrathiafulvenyl[4, 5-f]-[1, 10]phenanthroline (EDT-TTF-phen, 1). Its ruthenium(II) complex exhibits a unique packing of TTF subunits in the solid state. In an acetonitrile solution, [Ru(bpy) 2(1)](PF6)2 undergoes facile oxidative cleavage of the C=C double bond, which cannot be observed in the dark or under anaerobic conditions. This points to the photocatalytic role played by the ruthenium(II) chromophore in this conversion.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Product Details of 15746-57-3, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 15746-57-3, in my other articles.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI