In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.name: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Synthesis, characterization, and DNA binding of new water-soluble cyclopentadienyl ruthenium(II) complexes incorporating phosphines
The new water-soluble ruthenium(II) chiral complexes [RuCpX(L)(L?)] n+ (X = Cl, I. L = PPh3; L? = PTA, mPTA; L = L? = PTA, mPTA) (PTA = 1,3,5-triaza-7-phosphaadamantane; mPTA = N-methyl-1,3,5-triaza-7-phosphaadamantane) have been synthesized and characterized by NMR and IR spectroscopy and elemental analysis. The salt mPTA(OSO2CF3) was also prepared and fully characterized by spectroscopic techniques. X-ray crystal structures of [RuClCp(PPh 3)(PTA)] (2), [RuCpl(PPh3)(PTA)] (3), and [RuCpl(mPTA)(PPh3)](OSO2CF3) (9) have been determined. The binding properties toward DNA of the new hydrosoluble complexes have been studied using the mobility shift assay. The ruthenium chloride complexes interact with DNA depending on the hydrosoluble phosphine bonded to the metal, while the corresponding compounds with iodide, [RuCpl(PTA) 2] (1), [RuCpl(PPh3)(PTA)] (3), [RuCpl(mPTA) 2](OSO2CF3)2 (6), and [RuCpl(mPTA)(PPh3)](OSO2CF3) (9), do not bind to DNA.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI