246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium, molecular formula is C46H65Cl2N2PRu, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 246047-72-3, Quality Control of: (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium
An unexpected formation of a Ru(III) benzylidene complex during activation of a LatMet-type ring-opening polymerisation catalyst
Upon activation with C2Cl6 known latent Ru metathesis catalyst LatMet (13) exhibited activity in RCM and in ROMP of DCPD. A by-product of such activation, an aryloxybenzylidene ruthenium(III) complex 17 have been independently synthesised by reacting 13 with C2Cl6. This unique complex was characterised by spectroscopic and electrochemical methods, and by X-ray crystallography. To the best to our knowledge, this is the first isolated and structurally determined Ru(III) alkylidene complex reported.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium. In my other articles, you can also check out more blogs about 246047-72-3
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI