Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C41H35ClP2Ru. In my other articles, you can also check out more blogs about 32993-05-8
A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article£¬once mentioned of 32993-05-8, Computed Properties of C41H35ClP2Ru
The synthesis and structural characterisation of Ru-Sn based derivatives bearing asymmetric X2ClSn- (X = Br and F) anions
Four remarkable ruthenium-tin based derivatives [Ru(eta 5-Cp)(PPh3)2SnF2Cl] (1), [Ru(eta5-Cp)(PPh3)2SnBr2Cl] (2), [Ru(eta5-Cp)(dppe)SnF2Cl] (3) and [Ru(eta 5-Cp)(dppe)SnBr2Cl] (4), Cp = C5H5, were obtained by reacting [Ru(eta5-Cp)(PPh3) 2Cl] or [Ru(eta5-Cp)(dppe)Cl] with SnX2 {X = F or Br}, respectively. They were studied by i.r. NMR (1H, 13C, 31P and 119Sn) and 119Sn-Mo?ssbauer spectroscopies. Additionally, (1) and (4) were structurally authenticated by X-ray crystallography and the results were as follows: (1) orthorhombic, Pbca, V = 15181.7(12) A?3 and Z = 8; (4) monoclinic, P21/n, V = 3503.74(8) A?3 and Z = 4. All compounds exist as formulated only in the solid sate, in solution they re-distribute in a mixture of species such as [Ru(eta5-Cp)(PPh 3)2SnFnCl3-n] and [Ru(eta 5-Cp)(dppe)SnBrnCl3-n] {n = 0, 1, 2, and 3}, as revealed by variable temperature 119Sn NMR experiments.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C41H35ClP2Ru. In my other articles, you can also check out more blogs about 32993-05-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI