The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article£¬once mentioned of 37366-09-9, Formula: C12H12Cl4Ru2
Synthesis, characterization, and photochemical behavior of {Ru(arene)} 2+ derivatives of alpha-[PW11O39] 7-: An organometallic way to ruthenium-substituted heteropolytungstates
Reaction of [Ru(arene)Cl2]2 (arene = benzene, toluene, p-cymene, hexamethylbenzene) with K7[PW11O 39]¡¤14H2O provided two series of organometallic derivatives of heteropolytungstates: type-1 and type-2 complexes of general formulas [PW11O39{Ru(arene)(H2O)}]5- and [{PW11O39{Ru(arene)}}2{WO 2}]8-, respectively. All compounds were characterized by infrared and multinuclear NMR (1H, 31P, 183W) spectroscopies. The crystal structures of Na4K4-[{PW 11O39{Ru(benzene)}}2{WO2}] ¡¤6H2O (NaK-2a¡¤6H2O), K7H[{PW 11O39{Ru(toluene)}}2{WO2}] ¡¤4H2O (K-2b¡¤4H2O), and Cs3K 2[PW11O39{Ru(p-cymene)(H2O)}] ¡¤4H2O (CsK-1c-4H2O) were obtained and revealed that the {Ru(arene)} fragment is supported on the oxometallic framework. Photochemical reactivity of [PW11O39{Ru(arene)(H 2O)}]5- (arene = toluene, p-cymene) in the presence of various ligands L (L = H2O, dimethyl sulfoxide, tetramethylene sulfoxide, and diphenyl sulfoxide) was investigated, and led to the formation of [PW11O39{Ru(L)}]5-, in which the ruthenium is incorporated into the lacunary [PW11O39]7- anion.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Formula: C12H12Cl4Ru2, you can also check out more blogs about37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI