In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.HPLC of Formula: C41H35ClP2Ru
Cyanide-bridged arrays of 2, 3 and 4 metal atoms based on salene-iron complexes – Syntheses, structures and metal-metal interactions
Salene-Fe(III) complexes of the types LFeCl and [LFe(CN)2]- were treated with organometallic reagents to introduce the cyanide-linked units (CO)5Cr, (CO)5Mo, (CO)5W, Cp(CO)2Fe, Cp(dppe)Fe, and Cp(PPh3)2Ru. IR spectra and structure determinations revealed that all resulting complexes contained M-CN units with N coordination to the salene-Fe units. They were either dinuclear M-CN-Fe(salene), trinuclear M-CN-Fe(salene)-NC-M, or tetranuclear M-CN-Fe(salene)-Fe(salene)-NC-M species. Cyclic voltammetry showed that there are significant electronic interactions between the two outer organometallic units in the trinuclear complexes. UV/Vis spectra indicated a metal-metal charge transfer from the outer Cp(dppe)Fe groups to the central Fe(III). The magnetic moments at room temperature of the tri- and tetranuclear complexes are slightly lower than those calculated for isolated high-spin Fe(III) species.
Do you like my blog? If you like, you can also browse other articles about this kind. HPLC of Formula: C41H35ClP2Ru. Thanks for taking the time to read the blog about 32993-05-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI