Synthetic Route of 37366-09-9, Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a patent, introducing its new discovery.
The stannylene {2,6-(Me2NCH2)2C 6H3}SnCl as a ligand in transition metal complexes of palladium, ruthenium, and rhodium
The cleavage of the chloride bridge in the dimeric transition complexes [(eta3-C3H5)Pd]2(mu-Cl)2, [{eta6-benzene)RuCl]2(mu-Cl)2, [(eta6-cymene)RuCl]2(mu-Cl)2, [(CO) 3RuCl]2(mu-Cl)2, and [(CO) 2Rh]2(mu-Cl)2 by heteroleptic LSnCl stannylene (L is a N,C,N-pincer ligand [2,6-(Me2NCH2) 2C6H3]) resulted in the isolation of Pd II-SnII, RuII-SnII, and Rh I-SnII complexes [Pd(eta3-C3H 5)(LSnCl)Cl] (2), [Ra(eta6-benzene)(LSnCl)Cl 2] (3), [Ru(eta6-cymene)(LSnCl)Cl2] (4), [Ru(CO)3(LSnCl)Cl2] (5), and [Rh-(CO)2(LSnCl) Cl] (6). All compounds were characterized by NMR and IR spectroscopy, and the structures of compounds 2 and 4 were determined by X-ray diffraction analysis. The structure of a rare monomeric RhII – SnII complex, [Rh(LSnCl)2Cl2] (7), the final decomposition product of RhI – SnII complex 6, is also reported.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI