Related Products of 246047-72-3. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium. In a document type is Article, introducing its new discovery.
A CuI-Based Metallo-Supramolecular Gel-Like Material Built from a Library of Oligomeric Ligands Featuring Exotopic 1,10-Phenanthroline Units
A 22-membered cyclic alkene C1 incorporating an exotopic 1,10-phenanthroline nucleus in the ring skeleton has been synthesized and subjected to ring-opening metathesis polymerization (ROMP) in dilute dichloromethane solution at varying monomer concentrations (cmon). The resultant libraries of macrocyclic oligomers were used as ligands for the generation of main-chain metal-ligand oligomeric/polymeric complexes taking advantage of the strong affinity of 1,10-phenanthroline derivatives for CuI. The formation of a gel-like material only upon addition of [Cu(CH3CN)4]PF6 to the most concentrated library (cmon = 60 mM) was explained as arising from the presence of significant amounts of trimeric and higher oligomeric macrocycles Ci (i ? 3), acting as cross-linking components. A gel-like material has been obtained by exo coordination of CuI to the phenanthroline moieties of a library of multitopic cyclic ligands.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI