Synthetic Route of 92361-49-4, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 92361-49-4, C46H45ClP2Ru. A document type is Review, introducing its new discovery.
Reaction of Cp*RuCl(PPh3)2 with dioxygen and formation of a neutral complex Cp*RuCl(O2)(PPh3)
Reaction of Cp*RuCl(PPh3)2 (1) with atmospheric oxygen occurs at room temperature in the presence of acetone or methylene chloride leading to Cp*RuCl(O2)(PPh3) (2). This complex is remarkably stable in the solid state and it can also release, under not unduly harsh conditions, the activated oxygen molecule, which can oxidize the phosphite L = MeOP[ (OCHMe)2CH2] to the corresponding phosphate, along with formation of the mono- and disubstituted Cp*RuCl (PPh3)(L) (5), Cp*RuCl(L)2 (6) and [Cp*RuCl(PPh3)(L)2]Cl (7), complexes. Structural information of phosphite derivatives 5 and 6 has been obtained by X-ray diffraction.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI