If you are interested in 37366-09-9, you can contact me at any time and look forward to more communication.Electric Literature of 37366-09-9
Electric Literature of 37366-09-9, Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a patent, introducing its new discovery.
Homo- and Hetero-binuclear Complexes containing the Anion 2(pyrazolate)>- as Ligand. Crystal Structure of <(C5Me5)Rh2(mu-C3H3N2)Ru(C6H6)>ClO4*CH2Cl2
The neutral rhodium(III) complex > reacts with pyrazole-type ligands in the presence of AgClO4 yielding cationic complexes of the general formula (HL)>ClO4.They react with Na2CO3 in aqueous solutions with formation of the neutral complexes 2(HL)>.Addition of NaH in tetrahydrofuran to the cationic complexes or thallium acetylacetonate in MeOH to the neutral compounds affords the corresponding bimetallic derivatives <(C5Me5)Rh2LM> (M = Na or Tl).These complexes react with halide compounds such as <2> , , <(PtMe3I)4> or <2> (cod = cycloocta-1,5-diene) to give cationic or neutral complexes of the type <(C5Me5)Rh2(mu-L)M(ring)>ClO4 or <(C5Me5)Rh2(mu-L)MLn> .The crystal structure of <(C5Me5)Rh2(mu-pz)Ru(C6H6)>ClO4*CH2Cl2 has been determined by X-ray diffraction methods: monoclinic, space group P21/c, a = 11.179(1), b = 17.039(1), c = 18.186(2) Angstroem, beta = 94.85(1) deg and Z = 4.The complex cation consists of one rhodium and one ruthenium atom bridged by two phosphonate and one pyrazolate anion.An eta5-C5Me5 and an eta6-C6Me6 group complete the co-ordination spheres of the metals, which show no direkt intermetallic interaction.
If you are interested in 37366-09-9, you can contact me at any time and look forward to more communication.Electric Literature of 37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI