Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn¡¯t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery., Product Details of 32993-05-8
Helices of ruthenium complexes involving pyridyl-azine ligands: Synthesis, spectral and structural aspects
New cationic complexes [Ru(eta5-C5H5 (EPh3)(L)]BF4 [L = pyridine-2-carbaldehyde azine (paa); E = P, 1; E = As, 2; E = Sb, 3] and kappa1 bonded dppm complexes [Ru(eta5-C5H5 (kappa1-dppm)(L)]BF4 [L = paa 4; L = p-phenylene-bis(picoline)aldimine (pbp) 5] containing both group V donor and pyridyl-azine ligand are reported. The complexes were fully characterized by analytical and spectral studies. 31P NMR spectral studies suggested coordination of dppm in the complexes 4 and 5 in kappa1-manner, which was further, confirmed by structural studies on the representative complex 4. Weak interaction studies revealed that inter- and intramolecular C-H?X (X = O, F, Cl, pi) and pi-pi interactions in the complexes 1 and 4 lead to helical structures.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI