Final Thoughts on Chemistry for 20759-14-2

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Synthesis and characterization of the transition metal complexes: Their alcohol oxidation and electrochemical properties

Five Schiff base ligands, HA1, HA2, H 2L1-H2L3, and their Co(II), Mn(III) and Ru(III) complexes, have been synthesized and characterized by analytical, spectroscopic, conductance, magnetic moment, and electrochemical studies. The oxidation of benzylic alcohols to the corresponding carbonyl compounds is described. In the case of some primary benzyl alcohols, high conversions were obtained. Secondary benzyl alcohol (2-hydroxy-1,2-diphenylethanone derivatives) were selectively transformed to the corresponding ketone with satisfactory conversions. The electrochemical properties of all complexes have been recorded in the different scan rates and solvents. The electrochemical properties of the complexes change with scan rates. Taylor & Francis Group, LLC.

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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI