The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article£¬once mentioned of 37366-09-9, Recommanded Product: Dichloro(benzene)ruthenium(II) dimer
Synthesis, structure, and reactivity of RuII complexes with trimethylsilylethinylamidinate ligands
The mononuclear amidinate complexes [(eta6-cymene)-RuCl(1a)] (2) and [(eta6-C6H6)RuCl(1b)] (3), with the trimethylsilyl-ethinylamidinate ligands [Me3SiC?CC(N-c-C 6H11)2]- (1a-) and[Me3SiC?CC(N-i-C3H7)2] – (1b-) were synthesized in high yields by salt metathesis. In addition, the related phosphane complexes[(eta5- C5H5)Ru(PPh3)(1b)] (4a) [(eta5- C5Me5)Ru(PPh3)(1b)] (4b), and [(eta6-C6H6)Ru(PPh3)(1b)](BF 4) (5-BF4) were prepared by ligand exchange reactions. Investigations on the removal of the trimethyl-silyl group using [Bu 4N]F resulted in the isolation of [(eta6-C 6H6)Ru(PPh3){(N-i-C3H 7)2CC?CH}](BF4) (6-BF4) bearing a terminal alkynyl hydrogen atom, while 2 and 3 revealed to yield intricate reaction mixtures. Compounds 1a/b to 6-BF4 were characterized by multinuclear NMR (1H, 13C, 31P) and IR spectroscopy and elemental analyses, including X-ray diffraction analysis of 1b, 2, and 3. Copyright
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Recommanded Product: Dichloro(benzene)ruthenium(II) dimer, you can also check out more blogs about37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI