Discovery of 37366-09-9

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Synthetic Route of 37366-09-9. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer

Activation d’hydrogene par des complexes arene-ruthenium en solution aqueuse. III. Synthese de complexes hydrures heterometalliques ruthenium-rhodium

The low pressure hydrogenation of the hydrolysis mixture of (eta6-C6H6)2Ru2Cl4 in water leads, after removal of chloride by silver carboxylates, to the formation of dinuclear hydrido complexes of the type +.Analogously, the treatment of a mixture of (eta6-C6H6)2Ru2Cl4 and (eta6-C5Me5)2Rh2Cl4 with silver carboxylates and subsequent hydrogenation affords the mixed-metal monohydrido complexes <(eta6-C6H6)Ru(mu2-H)(mu2-OH)(mu2-eta2-O2CR)Rh(eta5-C5Me5)>+, containing two metal atoms in a chiral environment.The use of alpha-hydroxycarboxylates for this reaction causes the formation of the dihydrido complexes <(eta6-C6H6)Ru(mu2-H)2Rh(eta5-C5Me5)>+.The X-ray structure analyses of and <(eta6-C6H6)Ru(mu2-H)2Rh(eta5-C5Me5)> are reported.Keywords: Ruthenium; Rhodium; Hydrogen activation

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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI