Reference of 32993-05-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery.
Synthesis of the water soluble ligands dmPTA and dmoPTA and the complex [RuClCp(HdmoPTA)(PPh3)](OSO2CF3) (dmPTA = N,N?-dimethyl-1,3,5-triaza-7-phosphaadamantane, dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, HdmoPTA = 3,7-H-3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)
The new water-soluble ligand dmPTA(OSO2CF3) 2 (1) (dmPTA = N,N?-dimethyl-1,3,5-triaza-7-phosphaadamantane) has been synthesized by reaction of PTA with MeOSO2CF3 in acetone (PTA = 1,3,5-triaza-7-phosphatricycle[3.3.1.13,7]decane). The reaction of 1 with KOH gave rise to the new water-soluble ligand dmoPTA (3) (dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane) by elimination of the -CH2- group located between both NCH3 units. Compound dmPTA(BF4)2 (2) and complex [RuClCp(HdmoPTA)(PPh3)](OSO2CF3) (4) have also been synthesized, while compounds HdmoPTA(BF4) (3a) and [RuClCp(dmPTA)(PPh3)](OSO2CF3) (5) were characterized but not isolated. The new ligands and the complex have been fully characterized by NMR, IR, elemental analysis, and X-ray crystal structure determination (ligand 1 and complex 4). The synthetic processes for 3 and 4 were studied.
If you are hungry for even more, make sure to check my other article about 32993-05-8. Reference of 32993-05-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI