Electric Literature of 32993-05-8, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article£¬once mentioned of 32993-05-8
Extending metal-capped polyynediyl molecular wires by insertion of inorganic metal units
Several symmetric and asymmetric bis(metalla-diynediyl)ruthenium(II) complexes of the general formula trans-{LxRu} C?CC?C{Ru(dppe)2}C?CC?C{RuL? y} (Lx, L?y = (PPh3) 2Cp, (dppe)Cp, (dppe)Cp*), containing Ru(dppe)2 as the central linking group, have been successfully synthesized and characterized spectroscopically. DFT calculations show that their HOMO’s are delocalized over the Ru-C4-Ru-C4-Ru chain, suggesting that there is electronic interaction between the terminal RuLx groups through the C4 chains and the Ru(dppe)2 center. Limited electrochemical measurements reveal that the complexes undergo a series of five stepwise reversible or quasi-reversible oxidation processes.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 32993-05-8 is helpful to your research., Electric Literature of 32993-05-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI