Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn¡¯t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery., Formula: C41H35ClP2Ru
Spaltung aromatischer und vinylischer C-H-Bindungen durch Cyclopentadienylruthenium(II)-Komplexe
Neopentylruthenium complexes of the type Cp(MenPh3-nP)2RuCH2CMe3 (Cp = C5H5, C5Me5; n = 0-3) react with aromatic C-H bonds in benzene or toluene to give the corresponding phenyl- or tolyl-ruthenium compounds and neopentane.With toluene, a mixture of the m- and p-tolyl complexes is formed.The reactivity of the neopentylruthenium compounds decreases with increasing degree of methyl substitution at the phosphorus atom, and with bidentate phosphane ligands.A permethylated Cp group increases the reactivity. (C5Me5)(Me3P)2RuCH2CMe3 reacts also with the vinylic C-H bond of ethylene to form an (eta2-ethylene)vinylruthenium complex.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI