10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 10049-08-8, SDS of cas: 10049-08-8
KINETICS AND MECHANISM OF RUTHENIUM(III)-CATALYSED OXIDATION OF ALLYL ALCOHOL BY MOLECULAR OXYGEN.
Oxidation of allyl alcohol by molecular oxygen catalysed by ruthenium(III) chloride in the pH range 1. 0 – 3. 0 is reported. The kinetics of the reaction, in the pH range 1. 0 – 2. 0, indicate a first-order dependence on ruthenium(III) ion and allyl alcohol concentrations and a zero-order dependence with respect to molecular oxygen concentration. The rate of oxidation was also found to be directly proportional to the hydrogen ion concentration. In the pH range 2. 0 – 3. 0, the rate of oxidation of allyl alcohol was found to be first order with respect to ruthenium(III) ion, first order with respect to allyl alcohol, and inversely proportional to hydrogen ion concentration.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.SDS of cas: 10049-08-8. In my other articles, you can also check out more blogs about 10049-08-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI