A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II), molecular formula is C20H16Cl2N4Ru. In a Article£¬once mentioned of 15746-57-3, Formula: C20H16Cl2N4Ru
Binding of 9-Methylguanine to [cis-Ru(2,2?-bpy)2] 2+: First X-ray Structure of a cis-Bis Purine Complex of Ruthenium
Reaction of [cis-Ru(2,2?-bpy)2(O3SCF 3)2] (1) with 9-methylguanine (9-MeG) affords the cis-[Ru(2,2?-bpy)2(9-MeG)2]2+ complex (2) in good yield. Two bases bind to the metal center via the N7 atoms. X-ray structure analysis of 2(SO3CF3)2 (monoclinic, P21/n, a = 12.5159(6) A, b = 20.0904(13) A, c = 17.1202(9) A, beta = 98.981(6), V= 4252.1(4) A3, Z = 4) reveals that the two bases are in a head-to-tail (HT) orientation with base-base dihedral angle of 60.4. NMR studies confirm that the complex is stable in water for hours, and no evidence for guanine substitution by solvent molecules was found.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: C20H16Cl2N4Ru. In my other articles, you can also check out more blogs about 15746-57-3
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI