The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru. In a Article£¬once mentioned of 10049-08-8, HPLC of Formula: Cl3Ru
Electronic and geometrical manipulation of the excited state of bis-terdentate homo- and heteroleptic ruthenium complexes
This work describes the synthesis and characterization of two new bis-terdentate Ru(ii) complexes. Compound 1 is a homoleptic complex containing two CNC N-heterocyclic carbene (NHC) based ligands, whereas compound 2 bears one CNC ligand and an ancillary terpyridine ligand. The redox and photophysical properties of both compounds have been investigated and their X-ray crystal structures determined. Complex 1 displays a close-to-perfect octahedral coordination geometry and is not luminescent at room temperature while complex 2 features room temperature and 77 K luminescence despite its partially distorted geometry. The presence of the NHC moieties brings a significant amount of electronic density to the metal centre therefore lowering its oxidation potential with respect to that of analogous polypyridyl complexes. The Royal Society of Chemistry 2011.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.HPLC of Formula: Cl3Ru, you can also check out more blogs about10049-08-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI